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Research Publications

Exciting breakthroughs in nitrogen-rich energetic materials! Our latest research publications delve into innovative molecular designs, synthesis, and characterization of advanced energetic materials with applications in defense, aerospace, and civilian fields. Stay updated with our newest contributions to cutting-edge energetic materials and organic chemistry!

22. Trinitromethyl- and Nitramino-Substituted Triazolo-Pyridazines: Synthesis and Energetic Performance

Yadav, A. K.;‡ Nehe, S.;‡ Ghule, V. D.; Dharavath, S. (‡contributed equally)

Chem. Commun. 2025, Advance article.

21. Fused Azo-Bridged Triazolo-Pyridazine-Derived Energetic Materials

Yadav, A. K.;‡ Nehe, S.;‡ Ghule, V. D.; Dharavath, S. (‡contributed equally)

Org. Lett. 2025, Advance article.

20. Revisiting the Sensitive Nature of H-FOX: Interplay of Nitro and Hydrazine Functionalities to Construct Insensitive Energetic Material.

Yadav, A. K.; Ghule, V. D.; Dharavath, S.

Chem. Commun. 2025, 61, 6901 - 6904.

19. Employing Nitrogen–Sulfur Synergy: 1,2,3-Triazole-Thiadiazole-Based Energetic Materials.

Yadav, A. K.;‡ Kukreja, S.;‡ Dharavath, S. (‡contributed equally)

Org. Lett. 2025, 27, 2548–2553.

18. Highly Promising Primary Explosive: A Metal-Free, Fluoro-Substituted Azo-Triazole with Unmatched Safety, and Performance

Yadav, A. K.; Kukreja, S.; Dharavath, S.

JACS Au 2025, 5, 1031–1038.

17. Employing the trifluoromethyl group on 5/5 fused triazolo[4,3-b][1,2,4]triazole backbone: a viable strategy for attaining balanced energetics.

Yadav, A. K.;‡ Kukreja, S.;‡ Nehe, S.; Dharavath, S. (‡contributed equally)

Org. Lett. 2024, 26, 10611–10615.

16. Symmetric Refunctionalization of Diamino-dinitropyrazine with Hydrazine and Aminotetrazole: Strategy for Enhancing Detonation Performance and Safety in Energetic Materials.

Yadav, A. K.; Kukreja, S.; Nehe, S.; Ghule, V. D.; Dharavath, S.

Inorg. Chem. 2024, 63, 15144-15153.

15. Exploring the Explosive Potential: Synthesis and Characterization of Ring-Fused Oxadiazolo[3,4-b]pyrazine-1-Oxide Polymorphs with Balanced Energetic Properties.

Yadav, A. K.; Devi, R.; Ghule, V. D.; Dharavath, S.

Org. Lett. 2024, 26, 6006-6011.

14. Solvent-free Potassium 3,5-dinitro-6-oxo-1,6-dihydropyrazin-2-olate 3D EMOF as thermally stable energetic material.

Yadav, A. K.; Ghule, V. D.; Dharavath, S.

Chem. Asian J. 2024, 19, e202400409.

13. Elevating the energetic capabilities of metal coordination compound by incorporating nitrate anions.

Yadav, A. K.; Rajak, R.; Dharavath, S.

Dalton Trans. 2024, 53, 10093-10098.

12. Amine and nitramine functionalization of imidazole-triazine and triazole-triazine skeletons: Exploring for potential multipurpose energetic materials.

Yadav, A. K.; Jujam, M.; Ghule, V. D.; Dharavath, S.

J. Het. Chem. 2023, 61, 401-406.

11. Synthesis of Advanced Pyrazole and N-N-Bridged Bistriazole-Based Secondary High-Energy Materials

Yadav, A. K.; Kumar, N.; Ghule, V. D.; Dharavath, S.

Org. Lett. 2023, 25, 8606-8610.

10. Straightforward Synthesis of Insensitive 2-(1-Hydroxy-2,2-dinitro-vinyl)guanidine and Its Guanidinium Dinitromethanide Salt as a High Energy Density Material

Yadav, A. K.; Ghule, V. D.; Dharavath, S.

J. Org. Chem. 2023, 88, 13178-13183.

9. Energetic coordination compounds: self-assembled from the nitrogen-rich energetic C–C bonded pyrazoles and triazoles

Yadav, A. K.; Rajak, R.; Ghule, V. D.; Dharavath, S.

Dalton Trans. 2023, 52, 12271-12281. (Hot Article).

8. Thermally Stable and Insensitive Energetic Cocrystals Comprising Nitrobarbituric Acid Coformers

Yadav, A. K.; Ghule, V. D.; Dharavath, S.

Cryst. Growth Des. 2023, 23, 2826-2836.

7. High-Performing, Insensitive and Thermally Stable Energetic Materials from Zwitterionic Gem-Dinitromethyl Substituted C–C Bonded 1,2,4-Triazole and 1,3,4-Oxadiazole

Yadav, A. K.; Jujam, M.; Ghule, V. D.; Dharavath, S.

Chem. Commun. 2023, 59, 4324-4327. (ChemComm Most Popular 2023 Articles)

6. Promising Thermally Stable Energetic Materials with the Combination of Pyrazole-1,3,4-Oxadiazole and Pyrazole-1,2,4-Triazole Backbones: Facile Synthesis and Energetic Performance

Yadav, A. K.; Ghule, V. D.; Dharavath, S.

ACS Appl. Mater. Interfaces 2022, 14, 49898-49908.

5. Facile Fabrication of Functionalized Pyrimidine Derivatives: Constructing a New Family of High Performance and Less Sensitive Energetic Compounds

Yadav, A. K.; Ghule, V. D.; Dharavath, S.

J. Mater. Chem. A 2022, 10, 12702–12712.

4. Potential Energetic Salts of 5,5′-Methylenedi-(4H-1,2,4-Triazole-3,4-Diamine) Cation: Synthesis, Characterization and Detonation Performance

Mathpati, R. S.; Yadav, A. K.; Ghule, V. D.; Dharavath, S.

Energ. Mater. Front. 2022, 3, 90-96.

3. Unexpected Synthesis of Oxadiazole Analogues: Characterization and Energetic Properties

Yadav, A. K.; Kumar, P.; Ghule, V. D.; Dharavath, S.

Asian J. Org. Chem. 2022, 11, e202100779.

2. Unfolding the Chemistry of FOX-7: Unique Energetic Material and Precursor with Numerous Possibilities

Yadav, A. K.;‡ Banik, S.;‡ Kumar, P.;‡ Ghule, V. D.; Dharavath, S. (‡contributed equally)

Chem. Eng. J. 2021, 133378.

1. Dianionic Nitrogen-Rich Triazole and Tetrazole-Based Energetic Salts: Synthesis and Detonation Performance

Yadav, A. K.; D. Ghule, V.; Dharavath, S.

Mater. Chem. Front. 2021, 5, 8352-8360.

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